Approaching Asymmetry and Versatility in Polymer Assembly
Modern integrated circuits are produced in a “top-down” approach with the aid of lithographic techniques to sequentially control the etching and deposition of materials. Arbitrary nanoscale shapes can be created in a desired hierarchical sequence to produce a functional device. If assembled with no control of size, shape, or sequence, the same materials produce no function and no technology. In contrast to lithography, “bottom-up” solution processing can assemble nanoscale polymeric materials in a simple manner, often through aggregation and phase separation processes driven by multiple weak interactions and the minimization of free energy. Unfortunately, bottom-up products are usually relatively simple and symmetrical. [Science, 3 Aug 2012]